a new anode material for oxygen evolution in molten

Suresh Kannan Balasingam, PhD

However, in sea water electrolysis poisonous chlorine evolution is the most favored reaction over oxygen evolution at the anode. In this work, study has been focused on the development of electrode materials with high selectivity for oxygen evolution reaction over chlorine evolution.

Electrochemical growth of a corrosion

2018/7/20An in-situ formed three-layered scale consisting of a Cu-rich layer and two oxide layers on the surface of Ni10Cu11Fe alloy enables an inert anode for oxygen evolution reaction in molten Na 2 CO 3-K 2 CO 3.The outermost layer is mostly NiFe 2 O 4, the middle layer mainly consists of NiO, and the innermost is a Cu-rich metal layer.

Abiogenesis

In evolutionary biology, abiogenesis, or informally the origin of life (OoL), [3] [4] [5] [a] is the natural process by which life has arisen from non-living matter, such as simple organic compounds.[6] [4] [7] [8] While the details of this process are still unknown, the prevailing scientific hypothesis is that the transition from non-living to living entities was not a single event, but an

Crystals

Two-dimensional (2D) electron back scattered diffraction (EBSD) is a powerful tool for microstructural characterization of crystalline materials. EBSD enables visualization and quantification of the effect of synthesis methods on the microstructure of individual grains, thus correlating the microstructure to mechanical and electrical efficiency. Therefore, this work was designed to investigate

E51 V C Production of Oxygen Gas and Liquid Metal by Electrochemical Decomposition of Molten Iron

Molten oxide electrolysis (MOE) is the electrolytic decomposition of a metal oxide, most preferably into liquid metal and oxygen gas. The successful deployment of MOE hinges upon the existence of an inert anode capable of sustained oxygen evolution.

Primary Aluminum: Inert Anode and Wettable Cathode

2020/2/19US10415147 — ELECTRODE CONFIGURATIONS FOR ELECTROLYTIC CELLS AND RELATED METHODS — Elysis Limited Partnership (Canada) — In one embodiment, an electrolytic cell for the production of aluminum from alumina includes: at least one anode module with each module configured with a plurality of vertically oriented inert anodes; at least one cathode module, opposing the anode

Journal of Energy and Power Technology

Archiving: full-text archived in CLOCKSS. Rapid publication: manuscripts are peer-reviewed and a first decision provided to authors approximately 4.3 weeks after submission; acceptance to publication is undertaken in 6 days (median values for papers published in this journal in the first half of 2020, 1-2 days of FREE language polishing time is also included in this period).

MMO Anodes (Mixed Metal Oxide) for Cathodic

The catalytic life is significantly reduced when the primary reaction is the evolution of oxygen (fresh water, soil, coke backfill and concrete environments). Iridium Oxide (IrO 2 ) Most CP manufacturers use Iridium Oxide based mixed metal oxide for their cathodic protection anodes because it is suitable for both chlorinating and oxygenating environments.

Benchmarking of oxygen evolution catalysts on porous

The oxygen evolution reaction (OER) is the main anode reaction for electrochemical CO2 reduction and solar fuel production. We report a benchmarking study of some of the most active OER catalysts deposited on nickel foam and characterized by using a standardized protocol. The importance of the porosity of the support was highlighted as an important feature and led us to design a new dendritic

Frontiers

CO 2 can be valorized with three main routes. The "No transformation" route will not be described in this review as it is out of the scope of this article. With a "Chemical CO 2 conversion" route, it is technically possible to use CO 2 as a carbon source for the synthesis of commodity products, from simple CO to liquid fuels and high-molecular-weight polymers (Hu et al., 2013).

A cobalt metal–organic framework (Co

The oxygen electrocatalysis, i.e. the oxygen reduction and evolution reactions, is traditionally executed using noble metal and metal oxide-based nanostructures. However, they are associated with many disadvantages such as high cost, lower durability/selectivity and detrimental environmental effects; this motivates researchers to develop new electroactive materials.

Quantitative Analysis of Oxygen Gas Exhausted from

Quantitative analysis by in situ measurement of oxygen gas evolved from an anode was employed to monitor the progress of electrolytic reduction of simulated oxide fuel in a molten Li 2 O–LiCl salt. The electrolytic reduction of 0.6 kg of simulated oxide fuel was performed in 5 kg of 1.5 wt.% Li 2 O–LiCl molten salt at 650C.

Anodic Materials for Electrocatalytic Ozone Generation

Tin dioxide as anode, due to its high oxygen evolution potential, may inhibit the thermal dynamic favorable reaction for oxygen evolution. Using tin dioxide as anode material for electrolytic ozone generation was firstly mentioned by Foller and Tobias and it was considered as unsuitable anode material at that time [ 6 ].

Nickel based oxide film formed in molten salts for

Implementation of non-precious, active and durable catalysts towards the oxygen evolution reaction (OER) is a promising protocol addressing challenges in energy and environmental sustainability. Herein, a binder-free film composed of nickel ferrite is prepared by the anodic oxidation of a nickel alloy in molten

Solid oxide fuel cell

Introduction Solid oxide fuel cells are a class of fuel cells characterized by the use of a solid oxide material as the electrolyte.SOFCs use a solid oxide electrolyte to conduct negative oxygen ions from the cathode to the anode. The electrochemical oxidation of the hydrogen, carbon monoxide or other organic intermediates by oxygen ions thus occurs on the anode side.

Molten Oxide Electrolysis for Lunar Oxygen Generation using

150 New Boston St.; Woburn, MA, 01801, USA Keywords: ISRU, Molten Oxide Electrolysis, Inert Anode, Oxygen Generation Abstract Molten Oxide Electrolysis (MOE) is a promising and laboratory-proven in-situ resource utilization technology for

US Patent for Oxygen

If liquid anode is used, the oxygen dissolves in the liquid anode, [O] Anode, and evolves as oxygen gas O 2 (g). Liquid silver (Ag (l)) electrode serves as a medium to carry out the charge-transfer reaction involving oxygen ions and soluble oxygen at the YSZ/silver interface followed by oxygen gas evolution as shown in the above figure.

Electrolysis of iron in a molten oxide electrolyte

2018/1/5Allanore A, Yin L, Sadoway DR (2013) A new anode material for oxygen evolution in molten oxide electrolysis. Nature 497:353–357 CAS Article Google Scholar 8. Sirk AHC, Sadoway DR, Sibille L (2010) Direct electrolysis of molten lunar

Direct Conversion of Carbon Fuels in a Molten

article{osti_15014434, title = {Direct Conversion of Carbon Fuels in a Molten Carbonate Fuel Cell}, author = {Cherepy, N J and Fiet, K J and Krueger, R and Jankowski, A F and Cooper, J F}, abstractNote = {Anodes of elemental carbon may be discharged in a galvanic cell using a molten carbonate electrolyte, a nickel-foam anode-current collector, and a porous nickel air cathode to achieve power

A New Class of Zn 1

The scalable and cost-effective H 2 fuel production via electrolysis demands an efficient earth-abundant oxygen and hydrogen evolution reaction (OER, and HER, respectively) catalysts. In this work, for the first time, the synthesis of a sheet-like Zn 1-x Fe x-oxyselenide and Zn 1

Electrochemical Degradation Mechanism of a Cermet

When the cermet material is fully oxidized, metallic and oxide phases are converted into soluble or non-conductive phases, leading to the end of anode service life. Tests on (NixFeyO4 - Ni1?xFexO)/(CuxNiyFez) cermets, considered as promising anode for the aluminium production, were performed under electrolysis at 0.8 Acm-2 in molten mixture of cryolite at 960C.

Abiogenesis

In evolutionary biology, abiogenesis, or informally the origin of life (OoL), [3] [4] [5] [a] is the natural process by which life has arisen from non-living matter, such as simple organic compounds.[6] [4] [7] [8] While the details of this process are still unknown, the prevailing scientific hypothesis is that the transition from non-living to living entities was not a single event, but an

ELECTROCHEMICAL PROCESSING IN MOLTEN SALTS: FROM

electrolytes. Secon dly, to sustain oxygen evolution a carbon-free anode material must be found. Thirdly, the database is inadequate. To address the electrolyte issue a major research effort on a par with what accomp anied the molten salt breeder reactor must

Journal of Energy and Power Technology

Archiving: full-text archived in CLOCKSS. Rapid publication: manuscripts are peer-reviewed and a first decision provided to authors approximately 4.3 weeks after submission; acceptance to publication is undertaken in 6 days (median values for papers published in this journal in the first half of 2020, 1-2 days of FREE language polishing time is also included in this period).

US20200095696A1

A method of electrolytic reduction of a feedstock comprising oxygen and a first metal comprises the steps of, arranging the feedstock in contact with a cathode and a molten salt within an electrolysis cell, arranging an anode in contact with the molten salt within the

Metal Anode Clssification

The new insoluble titanium anode has high electrochemical catalytic energy, and the oxygen evolution overpotential is about 0.5 V lower than that of the lead alloy insoluble anode. It has significant energy saving, high stability, does not pollute the plating solution, is light in weight, and is easy to replace.

A new anode material for oxygen evolution in molten oxide

A new anode material for oxygen evolution in molten oxide electrolysis. [Antoine Allanore, Lan Yin, Donald R Sadoway] PMID 23657254 Abstract Molten oxide electrolysis (MOE) is an electrometallurgical technique that enables the direct production of metal in

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